A list of some of the available 400 MHz SSNMR experiments

• 90_times -- measured 90s and matching for 1.9 mm probe recently.

1D Experiments

• 1h.1p9 - single pulse proton
• h1_echo_20k.1p9 - 1D ¹H, 90-tau-180-tau-acq, vr=20khz, rotor syncd, better for baseline pulprog
• h1_echo_static.1p9 - 1D ¹H, 90-delay-180-delay-acq, vr=static pulprog
• 1H_background_removal_notes -- 1D 1H with background removal using the subtraction method in reference below. reference pulprog
• c13_dec.1p9 - ¹³C single pulse with tppm15 proton decoupling
• macro: cpmas_20k.1p9 -- ¹³C CPMAS optimized for spinning at 20 kHz. Be sure to be in Double Res Mode! (push up and turn to left counter clockwise looking from floor) pulprog phase_cycle
• macro: cpmas_13k.1p9 -- ¹³C CPMAS optimized for spinning at 13333. Be sure to be in Double Res Mode! (push up and turn to left counter clockwise looking from floor) pulprog phase_cycle
• cpmas_c90.1p9 - ¹³C CPMAS with flip-back pulse for calibrating ¹³C 90 time 90_CAL
• macro: cpmasNQS_20k.1p9 -- ¹³C non-quaternary suppression optimized for 20 kHz spinning, see only the quats NQS pulprog
• cppi_8k.1p9 - ¹³C CPMAS with polarization inversion; CH = null; CH2 = negative; C = positive; CH3 = positive (attenuated however); spin 8 kHz CPPI
• macro: multicp_14k.1p9 -- 1D 13C quantitative cpmas with multicp; vr=14k. pulprog reference
• dipinept.1p9 - ¹³C rapid acquisition (50ms D1) with dipolar inept for paramagnetically doped materials, vr=24khz reference
• hahnecho.1p9 - 90-tau-180-tau sequence for eliminating deadtime and baseline roll. set for paramagnetic 13C, vr=24khz, D1 150ms. reference
• macro: hahnecho_dec.1p9 -- 90-tau-180-tau sequence; cw/tppm15 1H dec; vr=20khz etc. pulprog
• cp_echo.1p9 - CP(500us) with Hahn-echo set for paramagnetic 13C, vr=20khz, D1 150ms. reference
• li7.1p9 - ⁷Li
• b11_dec.1p9 - ¹¹B single pulse with tppm15 proton decoupling review
• f19.1p9 - ¹⁹F single pulse Tuning_setup
• p31_20k.1p9 - ³¹P CPMAS spinning at 20kHz and tppm15 decoupling
• dipinept_p31.1p9 - ³¹P rapid acquisition (100ms D1) with dipolar inept for paramagnetically doped materials, vr=24khz reference
• kbr.1p9 - ⁷⁹Br (for setting Magic Angle) MA
• cpmas_gly.1p9 - ¹³C CPMAS used to set decoupling and cpmas conditions on Glycine OPT
• adam_c13.1p9 - ¹³C single pulse on Adamantane, set ¹³C 90 times, shimming and reference ADA
• adam_h1.1p9 - ¹H single pulse on Adamantane, set ¹H 90 times and reference ADA

2D Experiments

• hh_fprfdr.1p9 - 2D H/H correlation with Vr=20kHz; fprfdr 1.6ms mix (use for MOFs etc). pulprog reference
• wdqsq.1p9 - H/H DQ/SQ correlation with windowed acq, PMLG dec, and PC7 pumps. Vr=12.5kHz and NS=16 reference cramps_2d phase_cycle phase_pc7
• wdqsq64.1p9 - H/H DQ/SQ correlation with windowed acq, PMLG dec, and PC7 pumps. Vr=12.5kHz and NS=64(better selection) reference cramps_2d phase_cycle
• wpmlg2_hhcorr.1p9 - H/H SQ/SQ correlation with windowed acq, mix time 500us etc; Vr=12.5kHz and NS=16 reference distances cramps_2d
• dipinept2d.1p9 - ¹³C/¹H correlation having rapid acquisition (50ms D1) via dipolar inept for paramagnetically doped materials reference
• fslghetcor.1p9 - HETCOR ¹H/¹³C-correlation with Lee-Goldburg decoupling. Similar information to the HMQC. Vr=20kHz HETCOR
• cpinad_refoc.1p9 - Refocussed INADEQUATE for unlabelled sample. Vr=20kHz reference eDROOPY phase_cycle
• cpinad_zfr.1p9 - Z-filtered and Refocussed INADEQUATE for labelled and unlabelled sample. Vr=20kHz reference eDROOPY phase_cycle
• b11_mqmas_echo.1p9 - MQMAS ¹¹B-isotropic ¹¹B-anisotropic correlation. Split-t1 with shifted-echo acquisition and 20us z-filter (ie no shearing needed in processing). vr=20khz; ns=96*n MQMAS review
• b11_mqmas_zfil.1p9 - Basic 3-pulse MQMAS with z-filter for ¹¹B. Shearing (xfshear) is needed in processing MQMAS review
• hn_hmqc.1p9 - 1H/14N 2D-HMQC; natural abundance 14N reference

Local Field / Dynamics:

• macro: cpslf_13k.1p9 -- 2D H/C Separated Local Field (DIPSHIFT). vr = 13,333 Hz . Double Res Mode!
  
  • reference -- Reference paper
  • calc_slf.pl -- Calc Lee-Goldburg power levels / RF for set vr output
  • mk_slf.pl -- Calc t1 / delays. Creates file called "slf_list" slf_list
  • pulprog -- Current pulse sequence
  
  
• macro: cpslf2_13k.1p9 -- Double Dipolar Coupling 2D H/C Separated Local Field (2X-DIPSHIFT). vr = 13,333 Hz . Double Res Mode!
  
  • reference -- Reference paper
  • reference -- Reference paper 2x expt
  • calc_slf.pl -- Calc Lee-Goldburg power levels / RF for set vr output
  • mk_slf2.pl -- Calc t1 / delays. Creates file called "slf_list"
  • pulprog -- Current pulse sequence

13C/15N enriched:

1D:

• macro: cpmas_9k.1p9 -- 1D 13C cpmas with FB pulse for calibrating 90s; vr=9k. pulprog
• macro: cpmas_20k.1p9 -- 1D 13C cpmas with FB pulse for calibrating 90s; vr=20k. pulprog
• macro: cpmasN_9k.1p9 -- 1D 15N cpmas with FB pulse for calibrating 90s; vr=9k. pulprog

2D:

• macro: cprfdr_20k.1p9 -- C/C 2D finite pulse RFDR; Vr=20kHz, mix 2.8ms reference phase_cycle pulprog
• macro: cprfdr_9k.1p9 -- C/C 2D finite pulse RFDR with tppm/cw during mix; Vr=9kHz, mix 3.5ms reference phase_cycle pulprog
• macro: cpcord_20k.1p9 -- C/C 2D exchange using CORD; use instead of DARR; picks up aromatics and useful at high VR; no dipolar truncation (long distances measurable); Vr=20kHz, mix 200ms reference pulprog
• macro: cpdarr_20k.1p9 -- C/C 2D exchange DARR for strong contacts; Vr=20kHz, mix 50ms reference pulprog
• macro: cpdarr_13k.1p9 -- C/C 2D exchange DARR longer distances (7.5A); Vr=13kHz, mix 200ms reference pulprog
• macro: ncocx2d_9k.1p9 -- N/C NCoCx 2D; Vr=9kHz, fpRFDR mix 3.5ms with tppm/cw ref pulprog
• macro: ncacx2d_9k.1p9 -- N/C NCaCx 2D; Vr=9kHz, fpRFDR mix 3.5ms with tppm/cw ref pulprog
• macro: zftedor_9k.1p9 -- Z-filtered C->Ni 2D TEDOR; Vr=9kHz, mix 3.5ms with tppm/cw sims ref pulprog
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• macro: bstedor_9k.1p9 -- band-selective C->Ni 2D TEDOR; Vr=9kHz, mix 3.5ms with tppm/cw; C selected with gauss 180. sims ref pulprog
• macro: pithirds2_20k.1p9 -- pithirds dephasing for 13C/13C distance measurements. spinning 20khz and PSL detection used (see refs). reference -- reference -- macro_to_set_expt -- script_to_calc_loops/delays -- process_routine -- pulprog

3D:

• macro: ncocx3d_9k.1p9 -- NCoCx 3D; Vr=9kHz, DARR mix 50ms reference ref2 ref3 pulprog
• macro: ncacx3d_9k.1p9 -- NCaCx 3D; Vr=9kHz, DARR mix 25ms reference ref2 ref3 pulprog
• macro: conca3d_9k.1p9 -- CoNCa 3D; Vr=9kHz reference ref2 pulprog

Lithium experiments:

Lithium-7 1D:

• macro: li7_1d.1p9 -- single pulse 1D; Vr=20kHz; central transition largely selected -- pulprog
• macro: li7_solidecho.1p9 -- solid echo (90x-d9-90y) 1D; Vr=static; shows Hd and Hq -- ref -- phase_cycle -- pulprog
• macro: cpmasli_20k.1p9 -- 1H->7Li cpmas; Vr=20kHz; central transition largely selected; roughly ZQ (wi-ws)=wr matching still due to small Qcc -- ref -- pulprog -- calc_match

Lithium-7 2D:

• macro: li7_t1ir.1p9 -- T1 inversion recovery (180x-tau-90y-acq) pseudo 2D; Vr=20khz -- mk_t1ir_delays -- pulprog -- pulprog_syncd
• macro: li7_echo.1p9 -- pseudo 2D with hahn echo; Vr=xxkHz -- reference -- pulprog
• macro: li7_stimecho.1p9 -- pseudo 2D with stimulated echo; Vr=static -- ref -- pulprog -- mk_stimecho.pl -- delays -- phase_cycle (see supplement).

Lithium-6 1D:

• macro: li6_1d.1p9 -- single pulse 1D; Vr=20kHz; central transition largely selected -- pulprog

Lithium-6 2D:

• macro: li6_satrec.1p9 -- pseudo 2D saturation recovery for T1 ; Vr = 20kHz -- pulprog -- mk_satrec.pl -- satrec_delays