;selrogp ;avance-version (12/01/11) ;1D ROESY with cw spinlock for mixing ; using selective refocussing with a shaped pulse ; ;H. Kessler, H. Oschkinat, C. Griesinger & W. Bermel, ; J. Magn. Reson. 70, 106 (1986) ;J. Stonehouse, P. Adell, J. Keeler & A.J. Shaka, J. Am. Chem. Soc 116, ; 6037 (1994) ;K. Stott, J. Stonehouse, J. Keeler, T.L. Hwang & A.J. Shaka, ; J. Am. Chem. Soc 117, 4199-4200 (1995) ;A. Bax & D.G. Davis, J. Magn. Reson 63, 207-213 (1985) ; ;$CLASS=HighRes ;$DIM=1D ;$TYPE= ;$SUBTYPE= ;$COMMENT= #include #include # ifdef CALC_SPOFFS "spoff2=bf1*(cnst21/1000000)-o1" # else # endif /*CALC_SPOFFS*/ 1 ze 2 30m 20u pl1:f1 BLKGRAD d1 50u UNBLKGRAD (p1 ph1):f1 3u p16:gp1 d16 pl0:f1 p12:sp2:f1 ph2:r 3u p16:gp1 d16 pl11:f1 (p15 ph3):f1 go=2 ph31 30m mc #0 to 2 F0(zd) 20u BLKGRAD exit ph1=0 2 ph2=0 0 1 1 2 2 3 3 ph3=1 ph31=0 2 2 0 ;pl0 : 0W ;pl1 : f1 channel - power level for pulse (default) ;pl11: f1 channel - power level for ROESY-spinlock ;sp2: f1 channel - shaped pulse ;p1 : f1 channel - 90 degree high power pulse ;p12: f1 channel - 180 degree shaped pulse ;p15: f1 channel - pulse for ROESY spinlock ;p16: homospoil/gradient pulse [1 msec] ;d1 : relaxation delay; 1-5 * T1 ;d16: delay for homospoil/gradient recovery ;cnst21: chemical shift for selective pulse (offset, in ppm) ;ns: 8 * n, total number of scans: NS * TD0 ;ds: 4 ;phcor 2 : phasedifference between power levels sp1 and pl1 ;choose p12 according to desired selectivity ;the flip-angle is determined by the amplitude ;set O1 on resonance on the multiplet to be excited or use spoffs ;use gradient ratio: gp 1 ; 15 ;for z-only gradients: ;gpz1: 15% ;use gradient files: ;gpnam1: SMSQ10.100 ;$Id: selrogp,v 1.18 2012/01/31 17:49:28 ber Exp $